Thermodynamics & Heat
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RMS Molecular Speed

Root-mean-square speed of gas molecules.

Formula

vrms=3RTMv_{rms} = \sqrt{\frac{3RT}{M}}

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Variables

RGas constant
TTemperature
MMolar mass

How it works

This formula gives the root-mean-square speed, which is the single speed that represents the typical kinetic effect of a huge collection of gas molecules moving randomly in all directions. It comes from kinetic theory: the average translational kinetic energy of an ideal gas molecule is proportional to temperature, and because kinetic energy depends on speed squared, taking the square root of the mean of v^2 gives a meaningful “effective” speed. The dependence on molar mass shows that lighter molecules must move faster than heavier ones at the same temperature to have the same average kinetic energy.

When to use it

Use this when you need the characteristic molecular speed in an ideal gas, especially in kinetic theory, diffusion/effusion comparisons, or temperature-based gas behavior problems. It is also useful when comparing how changing temperature or molar mass affects molecular motion.

Worked example, step by step

Find the RMS speed of nitrogen gas, N2, at 350 K. Step 1: Write the formula: v_rms = sqrt(3RT/M) Step 2: Substitute values with SI units: R = 8.314 J mol^-1 K^-1 T = 350 K M = 28.0 g mol^-1 = 0.0280 kg mol^-1 Step 3: Calculate the numerator: 3RT = 3 × 8.314 × 350 = 8720.7 Step 4: Divide by molar mass: 8720.7 / 0.0280 = 311453.6 Step 5: Take the square root: v_rms = sqrt(311453.6) ≈ 558.1 m s^-1 Final answer: v_rms ≈ 5.58 × 10^2 m/s

Common mistakes to avoid

  • Using molar mass in g/mol instead of converting to kg/mol
  • Confusing RMS speed with average speed or most probable speed
  • Forgetting that the temperature must be in kelvin

Did You Know?

Air molecules around you zip along at roughly 500 m/s, faster than a jet, yet cancel out to no net wind.

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Reviewed & maintained by the FormulaWon editorial teamLast reviewed September 2026