Equilibrium Constant
Ratio of product to reactant concentrations at equilibrium.
Formula
Variables
Example
A large K means the reaction favours products at equilibrium.
How it works
The equilibrium constant compares how much product and reactant is present once a reversible reaction has settled into a steady state at a given temperature. Each concentration is raised to its stoichiometric coefficient because the balance condition from the reaction quotient is derived from the reaction’s stoichiometry, so changing the coefficients changes the sensitivity of the ratio. A very large or very small value tells you which side is favored at equilibrium, but the value itself is only meaningful for a specific temperature.
When to use it
Use this when analyzing reversible reactions in chemistry, especially to predict the equilibrium position or to compare a measured mixture with the expected equilibrium composition. It is also used in equilibrium calculations, such as finding an unknown concentration from known species at equilibrium.
Worked example, step by step
For the reaction: 2NO2(g) + F2(g) ⇌ 2NO2F(g) K = [NO2F]^2 / ([NO2]^2[F2]) Suppose at equilibrium: [NO2F] = 0.80 mol/L, [NO2] = 0.20 mol/L, and [F2] = 0.10 mol/L Substitute the values: K = (0.80)^2 / ((0.20)^2 × 0.10) K = 0.64 / (0.04 × 0.10) K = 0.64 / 0.004 K = 160 So, the equilibrium constant is K = 160.
Common mistakes to avoid
- Using initial concentrations instead of equilibrium concentrations
- Forgetting to raise concentrations to their stoichiometric powers
- Including pure solids or pure liquids in the equilibrium expression
Did You Know?
A large equilibrium constant means the reaction strongly favors products at balance.
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